THERMAL ANALYSIS IS
A BRANCH OF MATERIALS SCIENCE WHERE
THE PROPERTIES OF MATERIALS ARE STUDIED AS THEY CHANGE WITH TEMPERATURE. SEVERAL METHODS ARE COMMONLY USED – THESE ARE
DISTINGUISHED FROM ONE ANOTHER BY THE PROPERTY WHICH IS MEASURED:
·
DIELECTRIC THERMAL ANALYSIS (DEA):
DIELECTRIC PERMITTIVITY AND LOSS FACTOR
·
DIFFERENTIAL THERMAL ANALYSIS (DTA):
TEMPERATURE DIFFERENCE
·
DIFFERENTIAL SCANNING
CALORIMETRY (DSC): HEAT DIFFERENCE
·
DILATOMETRY (DIL): VOLUME
·
DYNAMIC MECHANICAL ANALYSIS (DMA) :
MECHANICAL STIFFNESS AND DAMPING
·
EVOLVED GAS ANALYSIS (EGA) :
GASEOUS DECOMPOSITION PRODUCTS
·
LASER FLASH ANALYSIS (LFA):
THERMAL DIFFUSIVITY AND THERMAL CONDUCTIVITY
·
THERMOGRAVIMETRIC ANALYSIS (TGA):
MASS
·
THERMOMECHANICAL ANALYSIS (TMA):
DIMENSION
·
THERMO-OPTICAL
ANALYSIS (TOA): OPTICAL PROPERTIES
SIMULTANEOUS
THERMAL ANALYSIS (STA) GENERALLY REFERS TO THE SIMULTANEOUS APPLICATION
OF THERMOGRAVIMETRY (TGA)
AND DIFFERENTIAL SCANNING
CALORIMETRY (DSC) TO ONE AND THE SAME SAMPLE IN A SINGLE
INSTRUMENT. THE TEST CONDITIONS ARE PERFECTLY IDENTICAL FOR THE TGA AND DSC
SIGNALS (SAME ATMOSPHERE, GAS FLOW RATE, VAPOR PRESSURE OF THE SAMPLE, HEATING
RATE, THERMAL CONTACT TO THE SAMPLE CRUCIBLE AND SENSOR, RADIATION EFFECT,
ETC.). THE INFORMATION GATHERED CAN EVEN BE ENHANCED BY COUPLING THE STA
INSTRUMENT TO AN EVOLVED GAS ANALYZER (EGA) LIKE FOURIER
TRANSFORM INFRARED SPECTROSCOPY (FTIR) OR MASS SPECTROMETRY
(MS).
OTHER,
LESS-COMMON, METHODS MEASURE THE SOUND OR LIGHT EMISSION FROM A SAMPLE, OR THE
ELECTRICAL DISCHARGE FROM A DIELECTRIC MATERIAL, OR THE MECHANICAL RELAXATION
IN A STRESSED SPECIMEN. THE ESSENCE OF ALL THESE TECHNIQUES IS THAT THE
SAMPLE'S RESPONSE IS RECORDED AS A FUNCTION OF TEMPERATURE (AND TIME).
IT IS USUAL TO
CONTROL THE TEMPERATURE IN A PREDETERMINED WAY - EITHER BY A CONTINUOUS
INCREASE OR DECREASE IN TEMPERATURE AT A CONSTANT RATE (LINEAR HEATING/COOLING)
OR BY CARRYING OUT A SERIES OF DETERMINATIONS AT DIFFERENT TEMPERATURES
(STEPWISE ISOTHERMAL MEASUREMENTS). MORE ADVANCED TEMPERATURE PROFILES HAVE
BEEN DEVELOPED WHICH USE AN OSCILLATING (USUALLY SINE OR SQUARE WAVE) HEATING
RATE (MODULATED TEMPERATURE THERMAL ANALYSIS) OR MODIFY THE HEATING RATE IN
RESPONSE TO CHANGES IN THE SYSTEM'S PROPERTIES (SAMPLE CONTROLLED THERMAL
ANALYSIS).
IN ADDITION TO
CONTROLLING THE TEMPERATURE OF THE SAMPLE, IT IS ALSO IMPORTANT TO CONTROL ITS
ENVIRONMENT (E.G. ATMOSPHERE). MEASUREMENTS MAY BE CARRIED OUT IN AIR OR UNDER
AN INERT GAS (E.G. NITROGEN OR HELIUM). REDUCING OR REACTIVE ATMOSPHERES HAVE
ALSO BEEN USED AND MEASUREMENTS ARE EVEN CARRIED OUT WITH THE SAMPLE SURROUNDED
BY WATER OR OTHER LIQUIDS. INVERSE GAS CHROMATOGRAPHY IS
A TECHNIQUE WHICH STUDIES THE INTERACTION OF GASES AND VAPOURS WITH A SURFACE -
MEASUREMENTS ARE OFTEN MADE AT DIFFERENT TEMPERATURES SO THAT THESE EXPERIMENTS
CAN BE CONSIDERED TO COME UNDER THE AUSPICES OF THERMAL ANALYSIS.
ATOMIC FORCE MICROSCOPY USES
A FINE STYLUS TO MAP THE TOPOGRAPHY AND MECHANICAL PROPERTIES OF SURFACES TO
HIGH SPATIAL RESOLUTION. BY CONTROLLING THE TEMPERATURE OF THE HEATED TIP AND/OR
THE SAMPLE A FORM OF SPATIALLY RESOLVED THERMAL ANALYSIS CAN BE CARRIED OUT.
THERMAL ANALYSIS IS
ALSO OFTEN USED AS A TERM FOR THE STUDY OF HEAT TRANSFER THROUGH STRUCTURES. MANY OF THE BASIC
ENGINEERING DATA FOR MODELLING SUCH SYSTEMS COMES FROM MEASUREMENTS OF HEAT CAPACITY AND THERMAL CONDUCTIVITY.
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